Rational Synthesis and Application of Aryl Iodides in Electrochemical Reactions and Theoretical Studies on the CBS Catalyst

Within this dissertation three different projects are discussed. The underlying theme of all projects is the application of computational and/or statistical methods in order to decrease the experimental effort and to increase the information output at the same time. Lewis acid activation of the CBS...

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Bibliographic Details
Main Author: Möckel, Robert
Contributors: Hilt, Gerhard (Prof. Dr.) (Thesis advisor)
Format: Doctoral Thesis
Language:English
Published: Philipps-Universität Marburg 2018
Subjects:
Online Access:PDF Full Text
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Summary:Within this dissertation three different projects are discussed. The underlying theme of all projects is the application of computational and/or statistical methods in order to decrease the experimental effort and to increase the information output at the same time. Lewis acid activation of the CBS catalyst was investigated using DFT theory. A new electrosynthetic approach for the synthesis of aryl iodides was developed using design of experiments. In a third project, a new iodide(III) mediated synthesis of isochromanones was investigated.
Physical Description:76 Pages
DOI:10.17192/z2018.0526