Nitrene-Mediated Asymmetric C-H Functionalizations with Chiral Ruthenium Complexes
Transition metal catalysis is a common tool for the synthesis of enantioenriched compounds and has been well-established in organic chemistry. Nitrene chemistry, a “hot area” in recent years, has proven to be very efficient in introducing C-N bonds due to the high value of amine-containing scaffolds...
Αποθηκεύτηκε σε:
| Κύριος συγγραφέας: | |
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| Άλλοι συγγραφείς: | |
| Μορφή: | Dissertation |
| Γλώσσα: | Αγγλικά |
| Έκδοση: |
Philipps-Universität Marburg
2023
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| Θέματα: | |
| Διαθέσιμο Online: | Πλήρες κείμενο PDF |
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| Περίληψη: | Transition metal catalysis is a common tool for the synthesis of enantioenriched compounds and has been well-established in organic chemistry. Nitrene chemistry, a “hot area” in recent years, has proven to be very efficient in introducing C-N bonds due to the high value of amine-containing scaffolds in various functional materials, natural products, and pharmaceuticals. This thesis presents novel catalytic asymmetric transformations mediated by a ruthenium nitrene intermediate and the synthesis as well as modification of new ruthenium complexes. |
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| Φυσική περιγραφή: | 262 Seiten |
| DOI: | 10.17192/z2023.0653 |