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Über die Darstellung 2,6-Di-iso-propylphenyl substituierter Bismutverbindungen und neuer bismuthaltiger Interpnictogenverbindungen
Ziel der vorliegenden Dissertation war die Darstellung neuer Interpnictogenverbindungen mit terminalen Diarylbismut-Einheiten. Die Darstellung erfolgte aus Verbindungen der Form Ar2BiX (X = F, Cl, Br), wobei als Aromaten Phenyl-, Mesityl und 2,6-Di-iso-propylphenyl-Substituenten eingesetzt wurden,...
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| Format: | Dissertation |
| Idioma: | alemany |
| Publicat: |
Philipps-Universität Marburg
2023
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| Accés en línia: | PDF a text complet |
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The goal of this work is the preparation of new interpnictogen compounds with terminal diaryl bismuth groups. These are prepared from compounds with the general formula Ar2BiX (X = Hal), whereby Phenyl, Mesityl and 2,6-di-iso-propylphenyl substituents are used for the investigation of steric effects on the stability of the prepared compounds. Most aryl halido bismuthanes with phenyl and mesityl substituents are already described in the literature. In contrast, the Dipp substituent is introduced as a substituent for bismuth in the course of this work. Moreover, the preparation of interpnictogen compounds with Bi-N, -P, -As and -Sb bonds was studied and the reactivity of the prepared compounds evaluated.