Publikationsserver
Synthese zweifach-koordinierter, quasilinearer Übergangsmetall(II/I)-Komplexe
Die vorliegende Arbeit beschäftigt sich mit der Synthese und Reaktivität der jungen und relativ unerforschten Substanzklasse (quasi-)linearer 3d-Metall(I)-Komplexe. Durch die elektronisch und koordinativ ungesättigten Metallzentren sind die Verbindungen sehr reaktiv, was in ersten Studien anhand der...
| 1. Verfasser: | |
|---|---|
| Beteiligte: | |
| Format: | Dissertation |
| Sprache: | Deutsch |
| Veröffentlicht: |
Philipps-Universität Marburg
2021
|
| Schlagworte: | |
| Online-Zugang: | PDF-Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
The present work deals with the synthesis and reactivity of the young and relatively unexplored substance class of (quasi-)linear 3d-metal(I) complexes. Due to the electronically and coordinatively unsaturated metal centers, the compounds are highly reactive as demonstrated in initial studies based on their reactivity towards small molecules and substrates. Insights into their magnetic behavior also indicate promising potential. However, only rare examples have been described in literature so far. This work contributes to the general understanding of the structural as well as magnetic properties and reactivities of silylamide-based metal(I) complexes and their metal(II) precursors. In addition, the spectrum of linear 3d metal(II) complexes has been extended to a complex with a phosphorus-based ligand system.