Synthesis and Design of Stereogenic-at-Metal Complexes and their Applications in Asymmetric Catalysis
Part 1: Post Complexation Cross-Coupling Reactions A straight forward method for post-complexation derivatizations of diastereomerically pure bis-cyclometalated benzoxazole and benzothiazole iridium(III) complexes was developed. Triflate- and bromide-functionalized iridium(III) complex dimers (sev...
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