Chiral-at-Metal Iridium(III) and Rhodium(III) Lewis Acid Catalysts for the α-Functionalization of 2-Acyl Imidazoles

Chiral-at-Metal Iridium(III) and Rhodium(III) Lewis Acid Catalysts for the α-Functionalization of 2-Acyl Imidazoles

This work describes the development of applications of chiral-at-metal iridium(III)- and rhodium(III) Lewis acid catalysts. Based on the reversible coordination to their metal center and enolization upon coordination, chiral Lewis acids are capable to facilitate various α-functionalizations of 2-acy...

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Autore principale: Zuo, Wei
Altri autori: Meggers, Eric (Prof. Dr.) (Relatore della tesi)
Natura: Dissertation
Lingua:inglese
Pubblicazione: Philipps-Universität Marburg 2017
Soggetti:
Fotokatalyse
Asymmetrische Katalyse
asymmetrische Katalyse
Fotokatalyse mit sichtbarem Licht
metallzentrierte Chiralität
Chemie
asymmetric catalysis
Lewis-Säure
iridium(III) complex
Rhodium(III)-Lewis-Säure
Iridium(III)-Lewis-Säure
visible-light driven photocatalysis
Rhodium(III) complex
chiral-at-metal Lewis acid catalysts
Chemistry & allied sciences
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Collocazione: urn:nbn:de:hebis:04-z2017-06669
Data di pubblicazione: 2018-04-05
Datum der Annahme: 2017-09-21
Downloads: 120 (2024), 107 (2023), 85 (2022), 45 (2021), 27 (2020), 20 (2019), 3 (2018)
Lizenz: https://creativecommons.org/licenses/by-nc-sa/4.0
URL di accesso: https://archiv.ub.uni-marburg.de/diss/z2017/0666
https://doi.org/10.17192/z2017.0666

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