Pentafluorphenylamide - von interessanten Liganden in der Seltenerdmetallchemie zu neuen Anionen in ionischen Flüssigkeiten
Die vorliegende Arbeit beschäftigt sich mit verschiedenen Aspekten der Chemie von Pentafluorphenylamiden. Dabei wurde die Eignung dieser nur wenig basischen N-Donoren für das Design sehr Lewis-acider Metallkomplexe getestet, wie auch deren Eignung als Anionen in hydrophoben ionischen Flüssigkeiten....
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| Định dạng: | Dissertation |
| Ngôn ngữ: | Tiếng Đức |
| Được phát hành: |
Philipps-Universität Marburg
2008
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| Truy cập trực tuyến: | Bài toàn văn PDF |
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The work deals with different aspects of the chemistry of pentafluorophenylamides. The applicability of these weakly basic N-donors both for the design of strongly Lewis acidic metal complexes and for the use as anions in ionic liquids. Thereby both bis(pentafluorophenyl)amide and a ligand derived from bisnephthylamide were used to generate complex compounds containing metal cations of the rare earth metals. Some of these compounds were tested in the ring opening polymerisation of epsilon-caprolactone. Furthermore a series of hydrophobic ionic liquids were synthesized containing pentafluorophenylamidoanions.