Design and Synthesis of Tris-Heteroleptic Bis-Cyclometalated Chiral-at-Rhodium Catalysts for Application in Asymmetric Catalysis

Design and Synthesis of Tris-Heteroleptic Bis-Cyclometalated Chiral-at-Rhodium Catalysts for Application in Asymmetric Catalysis

Chiral transition metal complexes represent a powerful class of catalysts for the asymmetric synthesis of optically active compounds. In recent years, Meggers and co-workers introduced a new class of iridium(III)- and rhodium(III)-based Lewis acid catalysts, in which the overall chirality exclusivel...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awdur: Grell, Yvonne
Awduron Eraill: Meggers, Eric (Prof. Dr.) (Cynghorydd traethodau ymchwil)
Fformat: Dissertation
Iaith:Saesneg
Cyhoeddwyd: Philipps-Universität Marburg 2021
Pynciau:
stereogenic metal
alpha-Halogenierungen
2+2 photocycloadditions
alpha-chlorination
Asymmetrische Katalyse
Rhodium
C1-Symmetrie
alpha-fluorination
Chemie
non-C2-symmetry
rhodium
oktaedrische Metallkomplexe
Asymmetric catalysis
chiral-at-metal
2+2 Photocycloadditionen
alpha-Fluorierung,
Metall-zentrierte Chiralität
Chemistry & allied sciences
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