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Organische Salze Sulfid- und Selenid-basierter Anionen: Bausteine für die Materialsynthese bi- und multinärer Metallchalkogenide
Eine Reihe organischer Salze mit chalkogenbasierten Anionen mit bisher unzugänglichen Kation-Anion Kombinationen wird beschrieben, zusammen mit deren Festkörperstrukturen und deren Eigenschaften in Lösung. Mögliche Wege zur Herstellung chalkogenbasierter Photovoltaikmaterialien CIGS und CZTS über Me...
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| Formato: | Dissertation |
| Idioma: | alemão |
| Publicado em: |
Philipps-Universität Marburg
2019
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| Assuntos: | |
| Acesso em linha: | Texto Completo em Formato PDF |
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A series of organic salts comprising chlacogenolate based anions and yet inaccessible cation-anion combinations is described. Solid state structures as well as their properties in solution were investigated. Possible syntheses for the preparation of photovoltaic materials CIGS and CZTS by utilizing metalate complex salts Cat[M(ESiMe3)(n+1)] are discussed. These complexes have been realised for M = Ga, In, Zn, Sn, Cu, Ag, Au (Cat = organic cation). The solid state structures of these novel metalate salts are discussed just as their thermal decay and their spectroscopic properties.