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Klassiker der Phosphorylidchemie als Gegenstand ortho-dirigierter Funktionalisierungen
Der Diskussionsteil der vorliegenden Arbeit gliedert sich in zwei Kapitel der Chemie orthofunktionalisierter Phosphorylide: Das Hauptkapitel II stellt Neues aus der Chemie der Carbodiphosphorane vor, in Kapitel III wird die Derivatisierung von Triphenylcyclopentadienylidenphosphoran (Ramirez-Ylid...
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| Formato: | Dissertation |
| Idioma: | alemão |
| Publicado em: |
Philipps-Universität Marburg
2017
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| Acesso em linha: | Texto Completo em Formato PDF |
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The discussion of the herein presented results on ortho-functionalized phosphorous ylides is divided into two parts: as the main section of this thesis, chapter II presents new developments in the chemistry of carbodiphosphoranes; in chapter III, the derivatization of triphenylcyclopentadienylidenephosphorane, the so-called “Ramires ylide”, is described. Through X-ray diffraction experiments, NMR, IR, UV/vis, fluorescence, and EPR spectroscopy, as well as mass spectroscopy and cyclic voltammetry, structural, chemical, and spectroscopical properties of the novel ligands and its main group and transition metal complexes were investigated.