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Charge Makes a Difference: Molecular Ionic Bismuth Compounds
Key challenges in modern synthetic chemistry include the design of reliable, selective, and more sustainable synthetic methods, as well as the development of promising candidates for new materials. Molecular bismuth compounds offer valuable opportunities as they show an intriguing spectrum of proper...
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| Những tác giả chính: | , , , |
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| Định dạng: | Bài viết |
| Ngôn ngữ: | Tiếng Anh |
| Được phát hành: |
Philipps-Universität Marburg
2023
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| Những chủ đề: | |
| Truy cập trực tuyến: | Bài toàn văn PDF |
| Các nhãn: |
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| Tóm tắt: | Key challenges in modern synthetic chemistry include the design of reliable, selective, and more sustainable synthetic methods, as well as the development of promising candidates for new materials. Molecular bismuth compounds offer valuable opportunities as they show an intriguing spectrum of properties that is yet to be fully exploited: a soft character, a rich coordination chemistry, the availability of a broad variety of oxidation states (at least +V to −I) and formal charges (at least +3 to −3) at the Bi atoms, and reversible switching between multiple oxidation states. All this is paired with the status of a non-precious (semi−)metal of good availability and a tendency towards low toxicity. Recent findings show that some of these properties only come into reach, or can be substantially optimized, when charged compounds are specifically addressed. In this review, essential contributions to the synthesis, analyses, and utilization of ionic bismuth compounds are highlighted. |
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| Mô tả vật lý: | 40 Seiten |
| DOI: | 10.1002/anie.202218771 |