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Bismuth Cations: Fluoride Ion Abstraction, Isocyanide Coordination, and Impact of Steric Bulk on Lewis Acidity
The molecular compound [BiDipp2(SbF6)], containing the bulky, donor-free bismuth cation [BiDipp2]+ has been synthesized and fully characterized (Dipp=2,6-iPr2-C6H3). Using its methyl analog [BiMe2(SbF6)] as a second reference point, the impact of steric bulk on bismuth-based Lewis acidity was invest...
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| Autoren: | , , , , , , , , |
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| Formato: | Artigo |
| Idioma: | inglês |
| Publicado em: |
Philipps-Universität Marburg
2023
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| Assuntos: | |
| Acesso em linha: | Texto integral em PDF |
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