Bismuth Cations: Fluoride Ion Abstraction, Isocyanide Coordination, and Impact of Steric Bulk on Lewis Acidity

Bismuth Cations: Fluoride Ion Abstraction, Isocyanide Coordination, and Impact of Steric Bulk on Lewis Acidity

The molecular compound [BiDipp2(SbF6)], containing the bulky, donor-free bismuth cation [BiDipp2]+ has been synthesized and fully characterized (Dipp=2,6-iPr2-C6H3). Using its methyl analog [BiMe2(SbF6)] as a second reference point, the impact of steric bulk on bismuth-based Lewis acidity was invest...

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Autori principali: Dunaj, Tobias, Schwarzmann, Johannes, Ramler, Jacqueline, Stoy, Andreas, Reith, Sascha, Nitzsche, Joel, Völlinger, Lena, Hänisch, Carsten von, Lichtenberg, Crispin
Natura: Articolo
Lingua:inglese
Pubblicazione: Philipps-Universität Marburg 2023
Soggetti:
Chemie
Chemistry & allied sciences
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