Between imide, imidyl and nitrene – an imido iron complex in two oxidation states

Between imide, imidyl and nitrene – an imido iron complex in two oxidation states

Imidyl and nitrene metal species play an important role in the N-functionalisation of unreactive C–H bonds as well as the aziridination of olefines. We report on the synthesis of the trigonal imido iron complexes [Fe(NMes)L2]0,- (L ¼ –N{Dipp}SiMe3); Dipp ¼ 2,6-diisopropyl-phenyl; Mes ¼ (2,4,6-trim...

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Autoren: Reith, Sascha, Demeshko, Serhiy, Battistella, Beatrice, Reckziegel, Alexander, Schneider, Christian, Stoy, Andreas, Lichtenberg, Crispin, Meyer, Franc, Munz, Dominik, Werncke, C. Gunnar
Format: Artikel
Jezik:angleščina
Izdano: Philipps-Universität Marburg 2022
Teme:
iron imide electronic structure
Chemie
Chemistry & allied sciences
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