Between imide, imidyl and nitrene – an imido iron complex in two oxidation states

Between imide, imidyl and nitrene – an imido iron complex in two oxidation states

Imidyl and nitrene metal species play an important role in the N-functionalisation of unreactive C–H bonds as well as the aziridination of olefines. We report on the synthesis of the trigonal imido iron complexes [Fe(NMes)L2]0,- (L ¼ –N{Dipp}SiMe3); Dipp ¼ 2,6-diisopropyl-phenyl; Mes ¼ (2,4,6-trim...

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Main Authors: Reith, Sascha, Demeshko, Serhiy, Battistella, Beatrice, Reckziegel, Alexander, Schneider, Christian, Stoy, Andreas, Lichtenberg, Crispin, Meyer, Franc, Munz, Dominik, Werncke, C. Gunnar
Format: Article
Language:English
Published: Philipps-Universität Marburg 2022
Subjects:
iron imide electronic structure
Chemie
Chemistry & allied sciences
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Call Number: urn:nbn:de:hebis:04-es2022-01011
Publication Date: 2022-07-18
Source: Erstveröffentlichung: Reith S, Demeshko S, Battistella B, et al. Between imide, imidyl and nitrene – an imido iron complex in two oxidation states. Chem. Sci. 2022;13(26):7907-7913. doi:10.1039/D2SC01088G
Downloads: 53 (2024), 51 (2023), 15 (2022)
License: https://creativecommons.org/licenses/by-nc-nd/4.0/
Access URL: https://archiv.ub.uni-marburg.de/es/2022/0101
https://doi.org/10.17192/es2022.0101

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