Two Faces of the Bi-O Bond: Photochemically and Thermally Induced Dehydrocoupling for Si-O Bond Formation

Two Faces of the Bi-O Bond: Photochemically and Thermally Induced Dehydrocoupling for Si-O Bond Formation

The diorgano(bismuth)alcoholate [Bi((C6H4CH2)2S)OPh] (1-OPh) has been synthesized and fully characterized. Stoichiometric reactions, UV/Vis spectroscopy, and (TD-)DFT calculations suggest its susceptibility to homolytic and heterolytic Bi-O bond cleavage under given reaction conditions. Using the de...

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Bibliographic Details
Main Authors: Ramler, Jacqueline, Schwarzmann, Johannes, Stoy, Andreas, Lichtenberg, Crispin
Format: Article
Language:English
Published: Philipps-Universität Marburg 2022
Subjects:
Chemie
Chemistry & allied sciences
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