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Cyclopentadienylidenphosphoran- und Diiminophosphinat-Liganden: Template in der metallorganischen Chemie der Alkali-, Erdalkali- und Seltenerdmetalle
Im Rahmen dieser Arbeit wurde die Koordinationschemie von Cyclopentadienylidenphosphoran-und Diiminophosphinat-Liganden mit ausgewählten s- und f-Block-Metallen untersucht. Der Fokus des ersten Kapitels lag auf der Bildung von Halbsandwich-Komplexen, von Constrained-Geometry-Komplexen und phosphorv...
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| Materyal Türü: | Dissertation |
| Dil: | Almanca |
| Baskı/Yayın Bilgisi: |
Philipps-Universität Marburg
2018
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| Online Erişim: | PDF Tam Metin |
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In this thesis the coordination chemistry of cyclopentadienylidene phosphorane and diiminophosphinate ligands with selected s- and f-block metals was investigated. The first chapter focused on the formation of zwitterionic half-sandwich complexes, constrained-geometry complexes and phosphorus bridged ansa-metallocenes based on different cyclopentadienylidene phosphorane ligands. In the second chapter the metallation of differently substituted diiminophosphinate ligands was investigated. A variety of homo- and heteroleptic complexes were realized. It was shown to what extent the steric demand and the donor properties of the investigated diiminophosphinate ligands stabilized homo- and heteroleptic complexes of the alkaline earth and rare earth metals.