N,C,N- und P,C,P-Carbodiphosphorane – Anwendungen als Chelatliganden und quantenchemische Analyse davon abgeleiteter und verwandter OLED-Emitter-Materialien
Innovative Beiträge dieser Dissertation finden sich im Bereich der metallorganischen Synthese neuartiger Carbodiphosphoran-Chelatliganden und ihrer Komplexe, in erstmaligen Untersuchungen zur Anwendung dieser Carbodiphosphorane als Template für OLED-Emitter- Komplexe sowie in der quantenchemischen...
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| Format: | Doctoral Thesis |
| Language: | German |
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Philipps-Universität Marburg
2021
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| Online Access: | PDF Full Text |
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The work in this dissertation focused on innovative contributions to the field of organometallic synthesis of novel chelating carbodiphosphorane ligands and their complexes. For the first time, these carbodiphosphoranes were examined regarding their ability to act as templates within photoluminescent complexes, which can be used in OLED devices. Furthermore, their frontier orbitals were examined in the ground state as well as in excited states using quantum chemical calculations, contributing to the fundamental understanding of their absorption and emission properties.