Design, Synthesis, and Application of a Nucleophilic Octahedral Stereogenic-Only-at-Metal Iridium(III) Catalyst

Design, Synthesis, and Application of a Nucleophilic Octahedral Stereogenic-Only-at-Metal Iridium(III) Catalyst

««Main Topic»» The design, synthesis, and application of a versatile chiral nucleophilic iridium(III) catalyst, which features a stereogenic octahedral metal center as its exclusive element of chirality ('stereogenic-only-at-metal'), is presented. The devised catalyst features two custom-...

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Bibliographic Details
Main Author: Cruchter, Thomas Josef
Contributors: Meggers, Eric (Prof. Dr.) (Thesis advisor)
Format: Doctoral Thesis
Language:English
Published: Philipps-Universität Marburg 2018
Subjects:
Cyanopyrrol
DFT
iridium
Reaktionsmec
Black Umlagerung
nucleophilic catalysis
Steglich Umlagerung
Lewis Base Katalyse
Cyclometallierung
organometallic chem
Organische Chemie
Iridium
asymmetric catalysis
Lewis base catalysis
Stereoinduktion
Asymmetrische Katalyse
acyl transfer
Benzoxazol
chiral-at-metal
Chemie
stereogenic-at-metal
Acyltransfer
Metallzentrierte Chiralität
Metallorganische Chemie
Nukleophile Katalyse
Chemistry & allied sciences
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Call Number: urn:nbn:de:hebis:04-z2018-01072
Publication Date: 2018-04-05
Date of Acceptance: 2018-03-22
Downloads: 151 (2024), 99 (2023), 59 (2022), 36 (2021), 31 (2020), 28 (2019), 83 (2018)
License: https://creativecommons.org/licenses/by-sa/4.0
Access URL: https://archiv.ub.uni-marburg.de/diss/z2018/0107
https://doi.org/10.17192/z2018.0107

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