Chiral-at-Metal Iridium(III) and Rhodium(III) Lewis Acid Catalysts for the α-Functionalization of 2-Acyl Imidazoles
This work describes the development of applications of chiral-at-metal iridium(III)- and rhodium(III) Lewis acid catalysts. Based on the reversible coordination to their metal center and enolization upon coordination, chiral Lewis acids are capable to facilitate various α-functionalizations of 2-acy...
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