Untersuchungen zur Synthese und Funktionalisierung verzweigter Tetrasilane

Ausgehend von dem, aus der Diplomarbeit bekannten, verzweigten Tetrasilan PhSi- (SiMe2PH2)3 konnten im ersten Teil dieser Arbeit Derivate mit den Erdalkalimetallen Calcium, Strontium und Barium sowie eine Verbindung mit Diisopropylgallium- Gruppen dargestellt und charakterisiert werden. Im zweit...

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Bibliographic Details
Main Author: Feierabend, Michael
Contributors: Hänisch, C. von (Prof. Dr.) (Thesis advisor)
Format: Doctoral Thesis
Published: Philipps-Universität Marburg 2013
Online Access:PDF Full Text
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Table of Contents: Starting from the synthesis of PhSi(SiMe2PH2)3, that has been described in the diploma thesis before, in this doctoral research study the alkaline earth metal complexes of calcium, strontium and barium as well as a compound with diisopropylgallium-groups were obtained and characterized. In the second part of this PhD-study, the branched silane PhSi(SiiPr2H)3 was obtained, chlorinated with TCCA to PhSi(SiiPr2Cl)3 and functionalized with the phosphorus-transfer-reagents [Li(dme)PH2], Li[AlPH2]4 and Li3P. The last part of the PhD-study is concerned with the synthesis of a siloxane bridged bicyclic compound and the reactions on the silicone bridgehead.