Die chemische Bindung in hochkoordinierten Übergangsmetallverbindungen
Die Natur der chemischen Bindung in experimentell bekannten zinkreichen Übergangsmetallverbindungen M(ZnR)n (n = 8-12) wird untersucht um die Existenz der ungewöhnlich hohen Koordinationszahlen zu verstehen. Die untersuchten Moleküle erinnern an endohedrale Cluster, es stellt sich aber heraus, dass...
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| Format: | Doctoral Thesis Dataset |
| Language: | German |
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Philipps-Universität Marburg
2011
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| Online Access: | PDF Full Text View Record |
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The nature of the chemical bond in experimentally known zinc-rich transition metal compounds M(ZnR) (n = 8-12) is investigated. at first glance these molecules appear to be endohedral clusters but the bonding analyses show that the stability of the molecules is caused by large radial interactions which are typical for coordination compounds.