Axial und peripher funktionalisierte Phthalocyanin- Oxo-, Imido- und Ureatokomplexe des Titans und Verwandter

Die vorliegende Arbeit beschäftigt sich mit neuen axial und peripher funktionalisierten Metallkomplexen der Phthalocyanine. Ein Schwerpunkt liegt bei Phthalocyaninen, deren Löslichkeit durch Substituenten am Ligandgerüst erhöht wurde. Insbesondere stellen Titan(IV)-Oxo- und davon abgeleitete Imido-...

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Bibliographic Details
Main Author: Käsmarker, Ralf
Format: Doctoral Thesis
Published: Philipps-Universität Marburg 2009
Online Access:PDF Full Text
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Table of Contents: The present work deals with new axially and peripherally functionalized metallophthalocyanines. A main focus lies on phthalocyanines, whose solubility was increased by introducing substituents into the periphery of the macrocycle. In particular titanium(IV)oxo and their imido and N,O-ureato derivatives are focus of the investigation. The latter are intermediates of a discovered metathesis of two isocyanate molecules to carbodiimides and carbon dioxide, which is catalyzed by oxo-titanium(IV)-phthalocyanine. This Thesis also gives a brief insight into the transferability of the introduced chemistry with respect to tungsten, molybdenum and vanadium as metal centers.