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Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical-Coupling Reactions (Pn =N, P, As)

The controlled release of well-defined radical species under mild conditions for subsequent use in selective reactions is an important and challenging task in synthetic chemistry. We show here that simple bismuth amide species [Bi(NAr2)3] readily release aminyl radicals [NAr2]C at ambient temperatur...

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Main Authors: Oberdorf, Kai, Hanft, Anna, Ramler, Jacqueline, Krummenacher, Ivo, Bickelhaupt, F. Matthias, Poater, Jordi, Lichtenberg, Crispin
Format: Article
Language:English
Published: Philipps-Universität Marburg 2023
Subjects:
aminyl radicals
Chemie
radical coupling
heavier pnictogens
bismuth amides
diphosphanes
Chemistry & allied sciences
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Call Number: urn:nbn:de:hebis:04-es2023-01737
Publication Date: 2023-11-21
Source: Erstveröffentlichung: Angew. Chem. Int. Ed. 2021, 60, 6441–6445. https://doi.org/10.1002/anie.202015514
Downloads: 60 (2025), 110 (2024), 7 (2023)
License: https://creativecommons.org/licenses/by-nc-sa/4.0
Access URL: https://archiv.ub.uni-marburg.de/es/2023/0173
https://doi.org/10.1002/anie.202015514

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