Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical-Coupling Reactions (Pn =N, P, As)

The controlled release of well-defined radical species under mild conditions for subsequent use in selective reactions is an important and challenging task in synthetic chemistry. We show here that simple bismuth amide species [Bi(NAr2)3] readily release aminyl radicals [NAr2]C at ambient temperatur...

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Bibliographic Details

Main Authors:	Oberdorf, Kai, Hanft, Anna, Ramler, Jacqueline, Krummenacher, Ivo, Bickelhaupt, F. Matthias, Poater, Jordi, Lichtenberg, Crispin
Format:	Article
Language:	English
Published:	Philipps-Universität Marburg 2023
Subjects:	Chemie heavier pnictogens radical coupling diphosphanes aminyl radicals bismuth amides Chemistry & allied sciences
Online Access:	PDF Full Text PDF Full Text
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