Dokument
| Titel: | Nitrene-Mediated Asymmetric C-H Functionalizations with Chiral Ruthenium Complexes |
| Autor: | Nie, Xin |
| Weitere Beteiligte: | Meggers, Eric (Prof.) |
| Veröffentlicht: | 2023 |
| URI: | https://archiv.ub.uni-marburg.de/diss/z2023/0653 |
| DOI: | https://doi.org/10.17192/z2023.0653 |
| DDC: | Chemie |
| Titel (trans.): | Nitren-Vermittelte Asymmetrische C-H Funktionalisierungen mit Chiralen Rutheniumkomplexen |
| Publikationsdatum: | 2024-11-18 |
| Lizenz: | https://rightsstatements.org/vocab/InC-NC/1.0/ |
| Schlagwörter: |
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| Oxygenation, Asymmetrische Aminierung, Asymmetrische C-H Funktionalisierung, Nitren, and Oxyamination, Oxygenierung, Ruthenium, Oxyaminierung, Asymmetric Amination |
Summary:
Transition metal catalysis is a common tool for the synthesis of enantioenriched compounds and has been well-established in organic chemistry. Nitrene chemistry, a “hot area” in recent years, has proven to be very efficient in introducing C-N bonds due to the high value of amine-containing scaffolds in various functional materials, natural products, and pharmaceuticals. This thesis presents novel catalytic asymmetric transformations mediated by a ruthenium nitrene intermediate and the synthesis as well as modification of new ruthenium complexes.
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