Publikationsserver der Universitätsbibliothek Marburg

Titel:Organische Funktionalisierung sowie intramolekulare Verknüpfung von Zinnchalkogenid-Clustern zur Darstellung von organisch-anorganischen Hybridverbindungen
Autor:Barth, Beatrix E. K.
Weitere Beteiligte: Dehnen, Stefanie (Prof. Dr.)
Veröffentlicht:2014
URI:https://archiv.ub.uni-marburg.de/diss/z2014/0368
URN: urn:nbn:de:hebis:04-z2014-03685
DOI: https://doi.org/10.17192/z2014.0368
DDC: Chemie
Titel (trans.):Organic Functionalization and Intramolecular Linkage of Tinchalcogenide Clusters Towards Organic-Inorganic Hybrid Compounds
Publikationsdatum:2014-07-23
Lizenz:https://rightsstatements.org/vocab/InC-NC/1.0/

Dokument

Schlagwörter:
crystallography, Chalkogene, cluster, Ligand, tin, chalcogens, metalorganic chemistry, ligand, Zinn, Cluster, Kristallographie, Metallorganische Chemie

Zusammenfassung:
Im Rahmen dieser Arbeit wurde die Chemie der organisch funktionalisierten Zinnchalkogenid-Cluster der generellen Zusammensetzung [(RfSn)xEy] (E = S, Se; Rf = organischer Ligand mit funktioneller Gruppe) erforscht und erweitert. Das Hauptaugenmerk lag dabei auf der Darstellung von binären und ternären Metallchalkogenid-Komplexen die mit funktionellen organischen Liganden ausgestattet sind und damit die Gruppe bekannter Liganden wie Carbonsäure-, Keto- oder Nitrilgruppen erweitern. Diese Liganden sollten das Potenzial besitzen Clustereinheiten inter- oder intramolekular zu verknüpfen um organisch-anorganische Hybridverbindungen zu schaffen. Daher wurden die direkte Anbindung geeigneter Moleküle an das Zinnatom (durch Einführung über die Cluster-Vorstufe Cl3SnRf) oder durch Erweiterung der bereits bestehenden Ligandensphäre durch Darstellung modifizierter Cluster [(RfSn)4S6] angestrebt.

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C220 0.062(12) 0.14(2) 0.103(16) -0.047(13) -0.040(12) 0.009(12) C301 0.041(8) 0.055(10) 0.063(9) -0.004(7) -0.029(6) -0.008(6) C302 0.053(8) 0.041(8) 0.056(9) -0.002(5) -0.030(7) 0.001(6) C303 0.048(9) 0.061(11) 0.070(12) -0.019(7) -0.026(8) -0.001(6) C304 0.051(8) 0.054(10) 0.052(10) -0.007(6) -0.032(8) -0.001(7) C307 0.037(8) 0.046(7) 0.059(7) 0.003(5) -0.027(6) -0.015(6) C308 0.027(8) 0.045(7) 0.059(7) 0.012(6) -0.018(6) -0.004(6) C310 0.042(9) 0.049(8) 0.066(8) 0.012(6) -0.028(6) -0.017(6) C311 0.050(10) 0.058(9) 0.058(8) -0.001(7) -0.026(7) -0.015(8) C312 0.064(12) 0.074(10) 0.048(9) 0.003(6) -0.019(8) -0.024(8) C313 0.068(11) 0.054(8) 0.045(7) 0.011(6) -0.026(6) -0.025(7) C314 0.047(9) 0.057(10) 0.049(8) 0.002(6) -0.032(6) 0.001(7) C315 0.051(10) 0.056(11) 0.098(14) -0.023(9) -0.035(10) -0.010(9) C316 0.044(9) 0.039(7) 0.069(10) 0.002(6) -0.030(7) -0.006(6) C318 0.20(3) 0.13(2) 0.28(3) 0.14(2) -0.22(3) -0.12(2) C319 0.111(18) 0.087(15) 0.21(2) 0.091(16) -0.124(17) -0.060(14) C320 0.064(12) 0.042(9) 0.108(14) 0.023(9) -0.052(10) -0.018(8) C321 0.061(11) 0.066(10) 0.062(11) 0.026(8) -0.033(8) -0.036(9) C401 0.082(12) 0.049(9) 0.050(9) 0.004(6) -0.014(8) -0.036(9) C402 0.056(8) 0.046(8) 0.041(8) 0.000(5) -0.011(6) -0.019(6) C403 0.060(7) 0.048(9) 0.045(9) 0.010(5) -0.021(6) -0.027(6) C404 0.039(7) 0.047(8) 0.036(8) 0.009(6) -0.012(6) -0.021(6) C407 0.032(8) 0.059(7) 0.048(7) -0.001(5) -0.012(7) -0.016(7) C408 0.041(10) 0.060(7) 0.057(7) -0.003(6) -0.017(8) -0.022(8) C410 0.059(12) 0.066(8) 0.070(9) -0.007(7) -0.036(10) -0.014(9) C411 0.064(12) 0.063(10) 0.062(9) 0.000(7) -0.033(9) -0.029(9) C412 0.056(11) 0.076(10) 0.055(9) -0.004(7) -0.018(9) -0.022(9) C413 0.046(10) 0.062(9) 0.061(8) -0.003(7) -0.018(8) -0.026(8) C414 0.050(9) 0.054(10) 0.045(8) 0.013(7) -0.009(7) -0.027(8) C415 0.057(8) 0.061(12) 0.059(10) 0.006(8) -0.009(7) -0.026(8) C416 0.050(9) 0.063(8) 0.055(8) 0.007(7) -0.031(6) -0.027(7) C418 0.064(10) 0.075(12) 0.051(9) 0.007(7) -0.022(7) -0.030(8) C419 0.072(11) 0.065(11) 0.069(10) 0.013(8) -0.046(8) -0.028(8) C420 0.066(11) 0.043(9) 0.075(10) -0.012(7) -0.030(7) -0.004(8) C421 0.068(10) 0.056(10) 0.064(10) -0.003(7) -0.033(7) -0.025(7) N5 0.065(9) 0.052(8) 0.046(6) 0.016(6) -0.034(6) -0.024(7) N6 0.045(7) 0.046(6) 0.051(6) 0.011(4) -0.016(5) -0.019(5) N9 0.033(7) 0.062(6) 0.055(6) 0.015(5) -0.018(6) -0.018(5) N17 0.040(7) 0.059(9) 0.061(8) 0.005(6) -0.013(6) -0.012(6) N205 0.044(7) 0.048(8) 0.031(5) 0.007(5) -0.016(5) -0.015(6) N206 0.061(8) 0.043(6) 0.039(5) 0.012(4) -0.017(5) -0.017(5) N209 0.067(8) 0.070(6) 0.039(5) 0.017(5) -0.027(6) -0.036(6) N217 0.061(9) 0.118(16) 0.118(13) -0.022(10) -0.034(9) -0.008(9) N305 0.051(7) 0.047(7) 0.061(8) -0.008(6) -0.033(6) -0.004(6) S6 0.2957(2) 0.30836(16) 0.15745(17) 0.0459(7) S7 0.1041(2) 0.37621(17) 0.34062(19) 0.0503(8) S8 0.0932(2) 0.21828(17) 0.2585(2) 0.0538(8) S9 0.3267(2) 0.09267(16) 0.17664(17) 0.0453(7) S10 0.2771(2) 0.17895(16) 0.36128(17) 0.0434(7) Zn1 0.61943(11) 0.13527(9) 0.37485(9) 0.0503(4) Zn2 0.58410(11) 0.41033(9) 0.16661(8) 0.0483(4) Zn3 0.23334(10) 0.11238(8) 0.11015(8) 0.0488(4) Zn4 -0.01062(11) 0.32745(9) 0.39832(9) 0.0552(4) Zn5 0.43587(10) 0.13433(8) 0.31851(7) 0.0437(3) Zn6 0.39225(10) 0.18677(8) 0.14457(8) 0.0454(3) Zn7 0.36407(10) 0.37662(7) 0.19968(7) 0.0418(3) Zn8 0.22643(10) 0.30741(7) 0.37685(8) 0.0438(3) Sn1 0.59694(6) 0.22626(5) 0.16946(4) 0.0436(2) Sn2 0.46168(6) 0.31593(5) 0.35991(4) 0.0432(2) Sn3 0.13832(6) 0.32786(4) 0.22261(5) 0.0478(2) Sn4 0.21273(6) 0.13067(4) 0.29409(5) C3 0.035(7) 0.059(8) 0.067(9) 0.017(7) -0.007(7) 0.007(6) C4 0.040(7) 0.038(7) 0.066(9) 0.005(6) -0.017(7) 0.001(6) C7 0.047(8) 0.048(8) 0.060(9) 0.015(7) -0.026(7) -0.017(6) C8 0.044(7) 0.049(8) 0.061(9) 0.014(7) -0.028(7) -0.011(6) C10 0.046(8) 0.051(8) 0.064(10) 0.018(7) -0.016(7) -0.012(7) C11 0.063(10) 0.060(9) 0.080(11) 0.032(9) -0.039(9) -0.017(8) C12 0.072(11) 0.053(10) 0.084(13) 0.014(10) -0.029(10) -0.018(9) C13 0.058(9) 0.038(7) 0.069(10) 0.016(7) -0.034(8) -0.010(6) C14 0.056(9) 0.069(10) 0.055(9) -0.019(7) 0.005(7) -0.017(8) C15 0.046(8) 0.074(10) 0.066(10) 0.013(8) -0.009(7) -0.019(7) C16 0.059(10) 0.075(11) 0.062(10) 0.009(9) -0.027(9) -0.024(9) C18 0.052(10) 0.096(13) 0.097(14) -0.025(11) -0.011(9) -0.020(9) C19 0.051(10) 0.115(15) 0.086(13) -0.031(11) -0.005(9) -0.021(10) C20 0.104(16) 0.17(2) 0.099(15) -0.057(15) -0.032(13) -0.063(16) C21 0.048(9) 0.133(16) 0.087(13) -0.042(12) -0.013(9) -0.020(10) C201 0.091(11) 0.097(12) 0.033(7) 0.007(7) -0.024(7) -0.055(10) C202 0.087(11) 0.073(9) 0.037(7) 0.002(6) -0.028(7) -0.047(9) C203 0.081(10) 0.060(8) 0.046(8) 0.003(6) -0.034(7) -0.029(8) C204 0.034(6) 0.050(7) 0.055(8) 0.005(6) -0.027(6) -0.009(6) C207 0.044(7) 0.031(6) 0.051(7) 0.005(6) -0.020(6) -0.015(6) C208 0.050(8) 0.049(8) 0.064(9) 0.021(7) -0.027(7) -0.026(7) C210 0.079(11) 0.104(13) 0.035(8) 0.008(8) -0.020(8) -0.046(10) C211 0.105(15) 0.125(16) 0.054(11) 0.032(12) -0.039(11) -0.074(14) C212 0.080(12) 0.073(11) 0.092(14) 0.050(11) -0.057(11) -0.033(10) C213 0.083(11) 0.055(9) 0.074(11) 0.005(8) -0.027(9) -0.031(9) C214 0.049(8) 0.066(9) 0.032(7) -0.016(6) 0.000(6) -0.015(7) C215 0.069(9) 0.059(8) 0.048(8) 0.016(6) -0.033(7) -0.023(7) C216 0.042(8) 0.064(10) 0.074(11) -0.019(8) -0.015(8) -0.015(7) C301 0.080(11) 0.043(9) 0.107(13) -0.026(9) -0.060(11) 0.002(8) C302 0.060(10) 0.040(9) 0.068(10) -0.006(8) -0.029(8) -0.001(8) C303 0.052(8) 0.031(7) 0.083(10) -0.016(6) -0.046(8) 0.013(6) C304 0.050(9) 0.058(9) 0.068(10) 0.002(7) -0.025(8) -0.013(7) C307 0.054(8) 0.052(9) 0.064(10) -0.004(7) -0.019(8) -0.026(7) C308 0.045(8) 0.050(8) 0.049(8) -0.007(7) -0.007(7) -0.010(7) C310 0.053(9) 0.065(10) 0.060(9) -0.018(8) -0.006(7) -0.019(8) C311 0.048(9) 0.069(10) 0.058(10) -0.021(8) 0.005(7) -0.011(8) C312 0.058(9) 0.088(12) 0.045(9) -0.018(9) -0.001(7) -0.026(9) C313 0.069(10) 0.090(12) 0.057(9) -0.003(9) -0.016(8) -0.043(10) C314 0.079(10) 0.047(8) 0.080(11) 0.000(7) -0.050(9) -0.006(7) C315 0.055(9) 0.073(10) 0.081(11) -0.036(8) -0.021(8) -0.016(8) C316 0.059(9) 0.053(8) 0.070(10) 0.001(7) -0.026(8) -0.021(7) C317 0.074(11) 0.061(10) 0.123(15) 0.012(10) -0.055(11) -0.018(8) C318 0.096(13) 0.079(12) 0.147(18) 0.052(12) -0.078(14) -0.046(11) C319 0.110(16) 0.094(14) 0.17(2) 0.050(14) -0.100(17) -0.050(13)
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