Publikationsserver der Universitätsbibliothek Marburg
Titel:Strukturchemie und Phasenbeziehungen der intermetallischen Phasen des Zweistoffsystems Iridium-Zink und ternärer Substitutionsvarianten mit Magnesium
Autor:Hornfeck, Wolfgang
Weitere Beteiligte: Harbrecht, Bernd (Prof. Dr.)
Veröffentlicht:2010
URI:https://archiv.ub.uni-marburg.de/diss/z2010/0560
DOI: https://doi.org/10.17192/z2010.0560
URN: urn:nbn:de:hebis:04-z2010-05602
DDC: Chemie
Titel (trans.):Structural chemistry and phase relations of the intermetallic phases of the binary iridium-zinc system and ternary substitutional variants with magnesium
Publikationsdatum:2010-10-13
Lizenz:https://rightsstatements.org/vocab/InC-NC/1.0/

Dokument

Schlagwörter:
Binary system, Strukturaufklärung, Intermetallische Verbindungen, Phasenbeziehungen, Iridium, Iridium, Strukturchemie, Structural chemistry, Intermetallic compounds, Zink, Binäres System, Phase relations, Zinc

Zusammenfassung:
Bericht über die erstmalige Synthese und Charakterisierung von intermetallischen Phasen des Zweistoffsystems Iridium-Zink, sowie einiger ternärer Substitutionsvarianten mit Magnesium. Die Synthese erfolgte mittels Hochtemperaturmethoden aus den Elementen. Zur Strukturaufklärung wurden Röntgenbeugungsexperimente an Einkristallen und Pulvern durchgeführt, ergänzt um transmissionselektronenmikroskopische Studien zur Realstruktur. Ausgewählte Präparate wurden hinsichtlich ihrer physikalischen Eigenschaften untersucht (thermisches Verhalten, Magnetismus, elektrische Leitfähigkeit). Diskutiert werden die Strukturchemie und Phasenbeziehungen, mit einem Schwerpunkt auf der struktursystematischen Einordnung der Befunde. Bemerkenswert sind das Auftreten einer zweidimensional inkommensurabel modulierten Phase (IrZn3), einer Phase mit dreidimensional ausgedehnter diffuser Streuung (IrZn2), sowie ganz allgemein der hohe Grad an struktureller Ausdifferenzierung und Komplexität, der sich an den binären Phasen - ihren Kristallstrukturen und Phasenbeziehungen - beobachten läßt.

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