Chiral-at-Metal Iridium(III) and Rhodium(III) Lewis Acid Catalysts for the α-Functionalization of 2-Acyl Imidazoles

Chiral-at-Metal Iridium(III) and Rhodium(III) Lewis Acid Catalysts for the α-Functionalization of 2-Acyl Imidazoles

This work describes the development of applications of chiral-at-metal iridium(III)- and rhodium(III) Lewis acid catalysts. Based on the reversible coordination to their metal center and enolization upon coordination, chiral Lewis acids are capable to facilitate various α-functionalizations of 2-acy...

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Dettagli Bibliografici
Autore principale: Zuo, Wei
Altri autori: Meggers, Eric (Prof. Dr.) (Relatore della tesi)
Natura: Dissertation
Lingua:inglese
Pubblicazione: Philipps-Universität Marburg 2017
Soggetti:
Fotokatalyse
Asymmetrische Katalyse
asymmetrische Katalyse
Fotokatalyse mit sichtbarem Licht
metallzentrierte Chiralität
Chemie
asymmetric catalysis
Lewis-Säure
iridium(III) complex
Rhodium(III)-Lewis-Säure
Iridium(III)-Lewis-Säure
visible-light driven photocatalysis
Rhodium(III) complex
chiral-at-metal Lewis acid catalysts
Chemistry & allied sciences
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