Asymmetric Catalysis with Octahedral Chiral-at-Metal Iridium and Rhodium Complexes
This thesis details the applications of a class of chiral-at-metal iridium(III) and rhodium(III) complexes for asymmetric catalysis. A rhodium-based asymmetric catalyst Δ-RhO is introduced which derives its optical activity from octahedral centrochirality. Besides serving as the exclusive source of...
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