Die chemische Bindung in hochkoordinierten Übergangsmetallverbindungen

Die Natur der chemischen Bindung in experimentell bekannten zinkreichen Übergangsmetallverbindungen M(ZnR)n (n = 8-12) wird untersucht um die Existenz der ungewöhnlich hohen Koordinationszahlen zu verstehen. Die untersuchten Moleküle erinnern an endohedrale Cluster, es stellt sich aber heraus, dass...

Full description

Saved in:
Bibliographic Details
Main Author: von Hopffgarten, Moritz
Contributors: Frenking, Gernot (Prof. Dr.) (Thesis advisor)
Format: Dissertation Dataset
Language:German
Published: Philipps-Universität Marburg 2011
Chemie
Subjects:
Online Access:PDF Full Text
View Record
Tags: Add Tag
No Tags, Be the first to tag this record!
Table of Contents: The nature of the chemical bond in experimentally known zinc-rich transition metal compounds M(ZnR) (n = 8-12) is investigated. at first glance these molecules appear to be endohedral clusters but the bonding analyses show that the stability of the molecules is caused by large radial interactions which are typical for coordination compounds.