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Titel:Asymmetric synthesis and applications of octahedral metal complexes
Autor:Lin, Zhijie
Weitere Beteiligte: Meggers, Eric (Prof. Dr.)
Veröffentlicht:2013
URI:https://archiv.ub.uni-marburg.de/diss/z2013/0234
URN: urn:nbn:de:hebis:04-z2013-02342
DOI: https://doi.org/10.17192/z2013.0234
DDC:540 Chemie
Titel (trans.):Asymmetrische Synthese und Anwendungen der Oktaedrischen Metallkomplexes
Publikationsdatum:2013-05-23
Lizenz:https://rightsstatements.org/vocab/InC-NC/1.0/

Dokument

Schlagwörter:
Asymmetric Octahedral Metal complexes, Asymmetrischer Oktaedrischer Metallkomplex

Summary:
In this thesis, some methods for the asymmetric synthesis of octahedral metal complexes were developed by using chiral auxiliaries. These chiral auxiliaries are coordinating bidentate ligands which control the metal-centered configuration in the course of ligand exchange reactions or dynamic equilibria. Afterwards, the chiral auxiliaries can be removed in an acid-induced fashion under complete retention of configuration. Additionally, we initially explored the applications of enantiomerically pure octahedral iridium complexes as catalysts for asymmetric transformations. In this direction, we focused on the asymmetric acyl transfer catalysis and synthesized different types of the catalysts for resolving racemic alcohols.


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