Dokument
Titel: | Asymmetric synthesis and applications of octahedral metal complexes |
Autor: | Lin, Zhijie |
Weitere Beteiligte: | Meggers, Eric (Prof. Dr.) |
Veröffentlicht: | 2013 |
URI: | https://archiv.ub.uni-marburg.de/diss/z2013/0234 |
URN: | urn:nbn:de:hebis:04-z2013-02342 |
DOI: | https://doi.org/10.17192/z2013.0234 |
DDC: | 540 Chemie |
Titel (trans.): | Asymmetrische Synthese und Anwendungen der Oktaedrischen Metallkomplexes |
Publikationsdatum: | 2013-05-23 |
Lizenz: | https://rightsstatements.org/vocab/InC-NC/1.0/ |
Schlagwörter: |
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Asymmetric Octahedral Metal complexes, Asymmetrischer Oktaedrischer Metallkomplex |
Summary:
In this thesis, some methods for the asymmetric synthesis of octahedral metal
complexes were developed by using chiral auxiliaries. These chiral auxiliaries are
coordinating bidentate ligands which control the metal-centered configuration in the course of ligand exchange reactions or dynamic equilibria. Afterwards, the chiral auxiliaries can be removed in an acid-induced fashion under complete retention of configuration.
Additionally, we initially explored the applications of enantiomerically pure
octahedral iridium complexes as catalysts for asymmetric transformations. In this direction, we focused on the asymmetric acyl transfer catalysis and synthesized different types of the catalysts for resolving racemic alcohols.
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